Degradation of bisphenol A by ozonation: Rate constants, influence of inorganic anions, and by-products

Abstract

The second-order rate constants for the reaction between bisphenol A (BPA) and ozone were evaluated over the pH range of 2-12. The rate constants showed minimum values (×104 M-1 s-1) under acidic condition (pH < 4) and were of maximum values (×109 M-1 s-1) under basic condition (pH >10). From pH 4 to 7, the second-order rate constants were found to increase by a magnitude of almost 102 and this was due to the increase in anionic BPA species in the solution. The rate constants increased almost twofold when pH increased from 9.6 to 10.2. The presence of common inorganic anions at levels commonly found in the environment did not affect the rate of degradation of BPA. The degradation by -products from the ozonation of BPA were identified as 4-(prop-1-en-2-yl)phenol, hydroquinone, 4-hydroxyacetophenone, 2-(2-(4-hydroxyphenyl)propan-2-yl)succinaldehyde, 2-(1-(4-hydroxyphenyl)vinyl)pent-2-enal, 3-formyl -4-(4-hydroxyphenyl)-4-methylpent-2-enoic acid, monohydroxy -BPA and dihydroxy-BPA. In conclusion, ozonation was found to be an effective method for the removal of BPA even in the presence of common inorganic anions at environmental concentrations. However, incomplete treatment of BPA might produce a variety of degradation by -products. © 2012 by Maejo University, San Sai, Chiang Mai, 50290 Thailand.