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Title: | Model studies on construction of the oxabicyclic [3.3.1] core of the mulberry Diels-Alder adducts morusalbanol A and 441772-64-1 | Authors: | Tee, J.T. Chee, C.F. Buckle, M.J.C. Lee, V.S. Chong, W.L. Khaledi, H. Rahman, N.A. |
Issue Date: | 2015 | Journal: | Tetrahedron Letters Volume 56, Issue 36, 1 August 2015, Pages 5082-5085 | Abstract: | Preparation of the oxabicyclic [3.3.1] cores of morusalbanol A and 441772-64-1 was achieved via the intramolecular cyclization of cis-trans (endo) mulberry Diels-Alder adducts. The latter were derived from a hydrogen bond-assisted regioselective Diels-Alder reaction between a chalcone dienophile and a dehydroprenyl diene. Results from these studies provide important insights into the syntheses of morusalbanol A and related mulberry Diels-Alder adducts. © 2015 Elsevier Ltd. All rights reserved. | DOI: | 10.1016/j.tetlet.2015.07.042 |
Appears in Collections: | COE Scholarly Publication |
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