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Please use this identifier to cite or link to this item: http://dspace.uniten.edu.my/jspui/handle/123456789/3717
Title: Efficient and eco-friendly syntheses of 1,5-benzothiazepines and 1,5-benzodiazepines catalyzed by [Hmim][NO3] under mild conditions
Authors: Loghmani-Khouzani, H. 
Tamjidi, P. 
Mohammadpoor-Baltork, I. 
Yaeghoobi, M. 
Rahman, N.A. 
Khosropour, A.R. 
Moghadam, M. 
Tangestaninejad, S. 
Mirkhani, V. 
Habibi, M.H. 
Kashima, A. 
Suzuki, T. 
Issue Date: 2014
Journal: Journal of Heterocyclic Chemistry Volume 51, Issue 1, January 2014, Pages 138-150 
Abstract: This article presents a synthetic method and reaction mechanism of the 1,5-benzothiazepines and 1,5-benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven-membered rings) have also been determined and compared with thiazine (six-membered ring). In this method, N-methylimidazolium nitrate [Hmim][NO3] has been used as a catalyst that acts as an environmental friendly system. © 2013 HeteroCorporation.
DOI: 10.1002/jhet.1827
Appears in Collections:COE Scholarly Publication

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