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dc.contributor.authorChee, C.F.
dc.contributor.authorLee, Y.K.
dc.contributor.authorBuckle, M.J.C.
dc.contributor.authorRahman, N.A.
dc.description.abstractThe mulberry Diels-Alder adducts, the pentamethyl ethers of kuwanon V 1a and dorsterone 2a were synthesised via a biomimetic intermolecular [4+2] cycloaddition reaction between a highly electron-rich dienophile and a Lewis acid sensitive diene derived from chalcone. Cycloaddition under thermal conditions afforded 1a and 2a (in 3:2 ratio). Cycloaddition catalysed by AgOTf/Bu4NBH4 gave higher yields of the adducts. © 2010 Elsevier Ltd. All rights reserved.
dc.titleSynthesis of (±)-kuwanon v and (±)-dorsterone methyl ethers via Diels-Alder reaction
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item.grantfulltextnone- Tenaga Nasional-
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