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http://dspace.uniten.edu.my/jspui/handle/123456789/9838
DC Field | Value | Language |
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dc.contributor.author | Saleh, M.I. | |
dc.contributor.author | Salhin, A. | |
dc.contributor.author | Saad, B. | |
dc.contributor.author | Zain, S.M. | |
dc.contributor.author | Rahman, N.A. | |
dc.contributor.author | Arifin, Z. | |
dc.date.accessioned | 2018-03-06T03:50:22Z | - |
dc.date.available | 2018-03-06T03:50:22Z | - |
dc.date.issued | 1998 | |
dc.identifier.uri | http://dspace.uniten.edu.my/jspui/handle/123456789/9838 | - |
dc.description.abstract | The structure of the complex salt, [C26H40N2O4][Nd(NO3)5(H2O)] (1), was determined by single crystal X-ray diffraction. It consists of alternating layers of the anionic complex, [Nd(NO3)5(H2O)]2-, and the cationic diprotonated [2H.azacrown]2+. The Nd3+ complex anion is coordinated to five bidentate nitrate ligands and a water ligand to give an 11-coordinated environment. Each Nd moiety is linked to another through intermolecular hydrogen bonding to form pairs of Nd moieties. The azacrown adopts a chair conformation and the benzyl groups are attached to the nitrogen atoms in an anti position with respect to each other, above and below the plane of the macro-ring in agreement with the conformation of the uncomplexed protonated azacrown as obtained by the PM3 method. | |
dc.title | A structural study of the interaction of dibenzyldiaza-18-crown-6 with neodymium(III) nitrate hexahydrate | |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
crisitem.author.dept | Universiti Tenaga Nasional | - |
Appears in Collections: | COE Scholarly Publication |
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